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Harmful and Potentially Harmful Constituents (HPHCs)

The Food, Drug and Cosmetic Act (FD&C Act) requires tobacco manufacturers and importers to report the levels of harmful and potentially harmful constituents (HPHCs) found in their tobacco products and tobacco smoke and/or aerosol. HPHCs are chemicals or chemical compounds that cause or could cause harm to users or non-users of tobacco products. 

FDA must publish HPHC quantities in each brand and subbrand of tobacco product, in a way that people find understandable and not misleading. FDA continues to research the best ways to communicate about:

  • the dangers posed by chemicals and chemical compounds in tobacco products and smoke and/or aerosol and
  • how to present HPHC levels in each brand and sub-brand of tobacco product so that they are clear and understandable.

In the meantime, FDA created three videos to lay the foundation for this important public health goal by exploring the chemicals in tobacco in three stages of cigarettes, from plant to product to puff. FDA also includes messages about HPHCs in its public health education.


HPHC List

FDA published a preliminary list of 93 HPHCs in March 2012, and updated the list with an additional 18 HPHCs in April 2026. The HPHC list focuses on chemicals that are linked to the five most serious health effects of tobacco use:

  • Cancer
  • Cardiovascular disease
  • Respiratory effects
  • Reproductive problems
  • Addiction  

FDA continues to review relevant science to determine whether to add additional constituents to the list. 

FDA is currently requesting comments on three proposed additions to the HPHC list: pulegone, furfuryl alcohol, and methyl eugenol. These constituents are often added to e-liquid formulations as flavoring ingredients, but may also be present in other tobacco products, such as cigarettes and smokeless tobacco. Public comments must be submitted by 11:59 p.m. ET on May 26, 2026, to ensure they are considered by FDA.

List of the Chemicals and Chemical Compounds Identified by FDA as Harmful and Potentially Harmful Constituents in Tobacco Products and Tobacco Smoke and/or Aerosol 

ConstituentReason for inclusion on HPHC list
AcetaldehydeCarcinogen, Respiratory Toxicant, Addictive
AcetamideCarcinogen
Acetic AcidRespiratory Toxicant
Acetoin (also known as 3-hydroxy-2-butanone)Respiratory Toxicant
AcetoneRespiratory Toxicant
Acetyl Propionyl (also known as 2,3-pentanedione)Respiratory Toxicant
AcroleinRespiratory Toxicant, Cardiovascular Toxicant
AcrylamideCarcinogen
AcrylonitrileCarcinogen, Respiratory Toxicant
Aflatoxin B1Carcinogen
4-AminobiphenylCarcinogen
1-AminonaphthaleneCarcinogen
2-AminonaphthaleneCarcinogen
AmmoniaRespiratory Toxicant
AnabasineAddictive
o-AnisidineCarcinogen
ArsenicCarcinogen, Cardiovascular Toxicant, Reproductive or Developmental Toxicant
A-α-C (2-Amino-9H-pyrido[2,3-b]indole)Carcinogen
Benz[a]anthraceneCarcinogen, Cardiovascular Toxicant
Benz[j]aceanthryleneCarcinogen
BenzeneCarcinogen, Cardiovascular Toxicant, Reproductive or Developmental Toxicant
Benzo[b]fluorantheneCarcinogen, Cardiovascular Toxicant
Benzo[k]fluorantheneCarcinogen, Cardiovascular Toxicant
Benzo[b]furanCarcinogen
Benzo[a]pyreneCarcinogen
Benzo[c]phenanthreneCarcinogen
Benzyl AcetateRespiratory Toxicant
BerylliumCarcinogen
1,3-ButadieneCarcinogen, Respiratory Toxicant, Reproductive or Developmental Toxicant
ButyraldehydeRespiratory Toxicant
CadmiumCarcinogen, Respiratory Toxicant, Reproductive or Developmental Toxicant
Caffeic acidCarcinogen
Carbon monoxideReproductive or Developmental Toxicant
CatecholCarcinogen
Chlorinated dioxins/furansCarcinogen, Reproductive or Developmental Toxicant
ChromiumCarcinogen, Respiratory Toxicant, Reproductive or Developmental Toxicant
ChryseneCarcinogen, Cardiovascular Toxicant
CobaltCarcinogen, Cardiovascular Toxicant
CoumarinBanned in food
Cresols (o-, m-, and p-cresol)Carcinogen, Respiratory Toxicant
CrotonaldehydeCarcinogen
Cyclopenta[c,d]pyreneCarcinogen
DiacetylRespiratory Toxicant
Dibenz[a,h]anthraceneCarcinogen
Dibenzo[a,e]pyreneCarcinogen
Dibenzo[a,h]pyreneCarcinogen
Dibenzo[a,i]pyreneCarcinogen
Dibenzo[a,l]pyreneCarcinogen
Diethylene GlycolPoisonous Chemical
2,6-DimethylanilineCarcinogen
Ethyl AcetateRespiratory Toxicant
Ethyl carbamate (urethane)Carcinogen, Reproductive or Developmental Toxicant
EthylbenzeneCarcinogen
Ethylene GlycolRespiratory Toxicant, Reproductive or Developmental Toxicant
Ethylene oxideCarcinogen, Respiratory Toxicant, Reproductive or Developmental Toxicant
FormaldehydeCarcinogen, Respiratory Toxicant
FuranCarcinogen
FurfuralRespiratory Toxicant
Glu-P-1 (2-Amino-6-methyldipyrido[1,2-a:3',2'-d]imidazole)Carcinogen
Glu-P-2 (2-Aminodipyrido[1,2-a:3',2'-d]imidazole)Carcinogen
GlycerolRespiratory Toxicant
GlycidolCarcinogen
HydrazineCarcinogen, Respiratory Toxicant
Hydrogen cyanideRespiratory Toxicant, Cardiovascular Toxicant
Indeno[1,2,3-cd]pyreneCarcinogen
IQ (2-Amino-3-methylimidazo[4,5-f]quinoline)Carcinogen
Isoamyl AcetateRespiratory Toxicant
Isobutyl AcetateRespiratory Toxicant
IsopreneCarcinogen
LeadCarcinogen, Cardiovascular Toxicant, Reproductive or Developmental Toxicant
MeA-α-C (2-Amino-3-methyl)-9H-pyrido[2,3-b]indole)Carcinogen
MercuryCarcinogen, Reproductive or Developmental Toxicant
Methyl AcetateRespiratory Toxicant
Methyl ethyl ketoneRespiratory Toxicant
5-MethylchryseneCarcinogen
4-(Methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK)Carcinogen
NaphthaleneCarcinogen, Respiratory Toxicant
n-ButanolRespiratory Toxicant
NickelCarcinogen, Respiratory Toxicant
NicotineReproductive or Developmental Toxicant, Addictive
NitrobenzeneCarcinogen, Respiratory Toxicant, Reproductive or Developmental Toxicant
NitromethaneCarcinogen
2-NitropropaneCarcinogen
N-Nitrosodiethanolamine (NDELA)Carcinogen
N-NitrosodiethylamineCarcinogen
N-Nitrosodimethylamine (NDMA)Carcinogen
N-NitrosomethylethylamineCarcinogen
N-Nitrosomorpholine (NMOR)Carcinogen
N-Nitrosonornicotine (NNN)Carcinogen
N-Nitrosopiperidine (NPIP)Carcinogen
N-Nitrosopyrrolidine (NPYR)Carcinogen
N-Nitrososarcosine (NSAR)Carcinogen
NornicotineAddictive
PhenolRespiratory Toxicant, Cardiovascular Toxicant
PhIP (2-Amino-1-methyl-6-phenylimidazo[4,5-b]pyridine)Carcinogen
Polonium-210 Carcinogen
Propionic AcidRespiratory Toxicant
PropionaldehydeRespiratory Toxicant, Cardiovascular Toxicant
Propylene GlycolRespiratory Toxicant
Propylene oxideCarcinogen, Respiratory Toxicant
QuinolineCarcinogen
SeleniumRespiratory Toxicant
StyreneCarcinogen
o-ToluidineCarcinogen
TolueneRespiratory Toxicant, Reproductive or Developmental Toxicant
Trp-P-1 (3-Amino-1,4-dimethyl-5H-pyrido[4,3-b]indole)Carcinogen
Trp-P-2 (1-Methyl-3-amino-5H-pyrido[4,3-b]indole)Carcinogen
Uranium-235Carcinogen, Respiratory Toxicant
Uranium-238Carcinogen, Respiratory Toxicant
Vinyl acetateCarcinogen, Respiratory Toxicant
Vinyl chlorideCarcinogen
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